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case western reserve university

MACROMOLECULAR SCIENCE AND ENGINEERING

 
 

PHOTOGALLERY

 

All the pictures or animations shown here are results obtained in our department by our research groups. Pictures cannot be reproduced without approval of the authors.

 

False color image of poly(N-isopropylacrylamide)/Clay Aerogel Temperature-Responsive Nanocomposite.
Picture: Schiraldi Research Group.

 
Simulation of bulk polymer concentration changing in time.
Picture: Chun-Chung Chen.

 
Flow pattern of a gas bubble in a room-temperature melt of poly(methylphenylsiloxane), which contains 0.1% w/w of BzPO. This 'caged' photoluminescent dye can be activated in a photochemical reaction; it was used, among other things, to bestow multilayer polymer mirrors with a 'hidden' photoluminescent pattern.
Picture: Christoph Kocher.

 
Polarized optical micrograph of bis(diphenylacetylene)Pt0 crystals. This low molecular weight organometalic complex was used as a model compound to confirm the chemical structure of poly(p-phenylene ethynylene)-Pt0 (PPE-Pt0) networks. The Pt0 cross-links significantly improve the charge transport characteristics of these semiconducting materials.
Picture: Akshay Kokil.

 
Lab sample of a fishing line based on the new polymeric material described here. The change of fluorescence color indicates that it may be time to change the line.
picture: Akshay Kokil.

 
Liquid crystal.
Picture: Oleg D. Lavrentovich.

 
Polarized optical microscopy image (crossed polarizers) of the nematic phase of 1,4-bis-(a-cyano-4-methoxystyryl)-benzene. The emission characteristics of blends of a host polymer and this and similar dyes strongly depend on the supramolecular architecture of the system. This dependence can be exploited by integrating such dyes as deformation sensors in a polymer of choice.
Picture: Christiane Löwe.

 
Pictures of polyethylene films which comprise traces of fluorescent dyes, which act as integrated deformation sensors.
Picture: Brent Crenshaw.

 
Polarized optical microscopy image (crossed polarizers) of a phase-separated blend of LLDPE and 1,4-bis-(a-cyano-4-methoxystyryl)-benzene. The emission characteristics of this and similar fluorescent polymer/dye blends strongly depend on the supramolecular architecture of the system.
Picture: Brent Crenshaw.

 
Optical micrograph of photoluminescent crystals of 1,4-bis-(a-cyano-4-methoxystyryl)-2,5-dimethoxybenzene. The emission characteristics of blends of a host polymer and this and similar dyes strongly depend on the supramolecular architecture of the system.
Picture: Akshay Kokil.

 
Optical micrograph of photoluminescent crystals of 1,4-bis-(a-cyano-4-methoxystyryl)-benzene. The emission characteristics of blends of a host polymer and this and similar dyes strongly depend on the supramolecular architecture of the system.
Picture: Brent Crenshaw.

 
Picture of photoluminescent crystals of 1,4-bis-(a-cyano-4-methoxystyryl)-2,5-dimethoxybenzene deposited on a glass substrate. The emission characteristics of blends of a host polymer and this and similar dyes strongly depend on the supramolecular architecture of the system.
Picture: Brent Crenshaw.

 
Simulation of mixing of two fluids in a single screw extruder.
Picture: Marco Camesasca.

 
Dissolution of an organometallic conjugated polymer in styrene, shown under illumination with UV-light. The dissolution of the originally cross-linked photoluminescent polymer demonstrates the reversibility of the ligand-exchange reaction that was employed to create the metallic cross-links between conjugated macromolecules. Such cross-links significantly improve the charge transport characteristics of these semiconducting materials.
Picture: Akshay Kokil.